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H1 Chemistry 8873 · Nov 2023ChemistryPaper 1Most challenging

Paper 1 Q15 — Which compound contains H⁻?

Redox — reduction is gain of electrons / decrease in oxidation number; the hydride ion

What the examiners said

“An understanding of the definition of reduction, in terms of gain in electrons or change in oxidation number, was required… that reduction of hydrogen gas produces H⁻ ions and that only sodium hydride contains this anion. The other three… are made when hydrogen… is oxidised.”

Try the question

In which compound has hydrogen been reduced (gained electrons) from H₂?
Examiner report: “Only sodium hydride contains H⁻; in the other three hydrogen is oxidised to +1.”

Explore — oxidation number of hydrogen

Pick a compound. The electronegativity comparison sets whether hydrogen is +1 (oxidised) or −1 (reduced, the hydride ion).

Reduction = gain of electrons = fall in oxidation number. Hydrogen only falls below zero (to −1) when bonded to a metal less electronegative than itself.

Original reconstruction inspired by the misconceptions described in the Singapore-Cambridge GCE A-Level H1 Chemistry 8873 November 2023 Examiner Report. Not the actual examination question. For classroom exploration.

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